This paper uses information entropy and coupling coordination evaluation to study the changes in land use structure and industrial structure, and the both coupling coordination of Boluo county during 2009 to 2016. Land use structure is rising at its information entropy and equilibrium and complexity, falling in dominance, indicating a more balanced and stable land use. The gross production is descending in information entropy and equilibrium, but increasing in dominance, implying an optimizing industrial structure. The tangible asset investment shows the contrary against the gross production, a more rational and balanced investment structure. The comprehensive index of land use structure and industrial structure is ascending, and so do their coupling coordination and coordinated development, between 0 to 1, close to 1, indicating a continued development of land use and industrial economy during the same period, with pace going with direction.